Holders Liverpool crashed out of the Champions League after being taken to extra-time at Anfield.
Jurgen Klopp’s men lost 3-2 to Atletico Madrid in the second leg of their last-16 match.
Llorente scored a double and Alvaro Morata struck the decisive goal in the 120th minute to give the Spanish side a 4-2 aggregate victory.
Elsewhere, Paris Saint-Germain progressed to the quarter-finals with a 3-2 aggregate win over Borussia Dortmund.
Trailing 2-1 from the first leg in Dortmund, the Ligue 1 champions levelled the tie when Neymar netted just before the half-hour mark and Juan Bernat gave them the lead in first-half stoppage time.
Bergs shocks Alcaraz in Shanghai as Zverev claims year-end top ranking
Ten arrested and police officer injured after Manchester City’s win at Liverpool
Australia need six wickets on final day to win first Test
Red Bull's Verstappen wins Singapore Grand Prix
